Barcelona bermain imbang 3-3 melawan Club Brugge, sementara Chelsea ditahan Qarabag 2-2 di Baku.
Kedua tim kini sama-sama mengoleksi tujuh poin dan menempati posisi ke-11 dan ke-12 klasemen sementara.
Berikut hasil lengkap dan klasemen matchday 4 Liga Champions 2025/26:
Pafos 0–1 Villarreal
Qarabag 2–2 Chelsea
Newcastle United 2–0 Athletic Club
Marseille 0–1 Atalanta
Manchester City 4–1 Borussia Dortmund
Inter Milan 2–1 Kairat Almaty
Club Brugge 3–3 Barcelona
Benfica 0–1 Bayer Leverkusen
Ajax 0–3 Galatasaray
| No | Tim | Main | Menang | Seri | Kalah | Poin |
| 1 | Bayern Muenchen | 4 | 4 | 0 | 0 | 12 |
| 2 | Arsenal | 4 | 4 | 0 | 0 | 12 |
| 3 | Inter Milan | 4 | 4 | 0 | 0 | 12 |
| 4 | Manchester City | 4 | 3 | 1 | 0 | 10 |
| 5 | Paris St-Germain | 4 | 3 | 0 | 1 | 9 |
| 6 | Newcastle United | 4 | 3 | 0 | 1 | 9 |
| 7 | Real Madrid | 4 | 3 | 0 | 1 | 9 |
| 8 | Liverpool | 4 | 3 | 0 | 1 | 9 |
| 9 | Galatasaray | 4 | 3 | 0 | 1 | 9 |
| 10 | Tottenham Hotspur | 4 | 2 | 2 | 0 | 8 |
| 11 | Barcelona | 4 | 2 | 1 | 1 | 7 |
| 12 | Chelsea | 4 | 2 | 1 | 1 | 7 |
| 13 | Sporting CP | 4 | 2 | 1 | 1 | 7 |
| 14 | Borussia Dortmund | 4 | 2 | 1 | 1 | 7 |
| 15 | Qarabag SK | 4 | 2 | 1 | 1 | 7 |
| 16 | Atalanta | 4 | 2 | 1 | 1 | 7 |
| 17 | Atletico Madrid | 4 | 2 | 0 | 2 | 6 |
| 18 | PSV Eindhoven | 4 | 1 | 2 | 1 | 5 |
| 19 | AS Monaco | 4 | 1 | 2 | 1 | 5 |
| 20 | Pafos FC | 4 | 1 | 2 | 1 | 5 |
| 21 | Bayer Leverkusen | 4 | 1 | 2 | 1 | 5 |
| 22 | Club Brugge | 4 | 1 | 1 | 2 | 4 |
| 23 | Frankfurt | 4 | 1 | 1 | 2 | 4 |
| 24 | Napoli | 4 | 1 | 1 | 2 | 4 |
| 25 | Marseille | 4 | 1 | 0 | 3 | 3 |
| 26 | Juventus | 4 | 1 | 3 | 0 | 6 |
| 27 | Athletic Club | 4 | 1 | 0 | 3 | 3 |
| 28 | Union St.Gilloise | 4 | 1 | 0 | 3 | e |
| 29 | Bodo/Glimt | 4 | 0 | 2 | 2 | 2 |
| 30 | Slavia Praha | 4 | 0 | 2 | 2 | 2 |
| 31 | Olympiakos | 4 | 0 | 2 | 2 | 2 |
| 32 | Villarreal | 4 | 0 | 1 | 3 | 1 |
| 33 | Fc Kopenhagen | 4 | 0 | 1 | 3 | 1 |
| 34 | Kairat Almaty | 4 | 0 | 1 | 3 | 1 |
| 35 | Benfica | 4 | 0 | 0 | 4 | 0 |
| 36 | Ajax | 4 | 0 | 0 | 4 | 0 |
